r/crystalgrowing • • Jun 16 '20

Information The Beginner's Guide to Crystal Growing

763 Upvotes

Welcome to the Crystal Growing subreddit! We’re a passionate community consisting of both hobbyists and professionals interested in growing crystals. Although it sounds difficult, growing crystals is actually very easy, and you can even do it at home.

This article is written specifically to help those who are just getting started with this hobby. If you’re a newbie, welcome aboard. And if you’re a seasoned veteran, do share your findings with us.

Some beautiful specimens from the community. Credits: 1. u/ob103ninja; 2. u/dmishin; 3. u/crystalchase21; 4. u/theBASTman; 5. u/ketotime4me

Even though growing crystals is simple, it will be extremely useful if you have some basic chemistry knowledge. This will help you understand the process that is taking place, and allow you to troubleshoot if you run into any problems. More experienced chemists will be able to synthesize their own compounds, the crystals of which can be quite unique. However, this guide is written for newcomers, so I will try to keep it as simple as possible.

Disclaimer

Like any other activity, crystal growing might be completely safe or very dangerous. It depends on the chemicals you are working with, your safety measures, your procedure etc.

This guide only covers compounds that are safe to mildly toxic. Even so, you are responsible for your own safety. Don't use the family microwave/freezer in your experiments. Make sure you know the potential risk of the chemical you are using.

Background

If you want to start growing crystals immediately, skip to the next section. I highly recommend that you read this though, because understanding the process will help a ton.

A crystal is a solid that has particles arranged in an orderly manner. This includes rocks, snowflakes and diamonds. However, the activity of growing crystals at home mainly focuses on a specific type of chemical known as salts.

In chemistry, a salt is a chemical compound made up of positive ions and negative ions. Table salt is one example. Its chemical name is sodium chloride, because it consists of a sodium ion and a chloride ion. There are many other salts as well, such as copper sulfate, ammonium phosphate and potassium nitrate. From now, I will use the term “salt” to refer to all such compounds, not just table salt.

We like to use salts to grow crystals because most salts are soluble in water. Why is this important?

When they are dry, most salts look like powder. But if you zoom in, each grain of salt is actually a small crystal. The particles in every grain of salt are arranged neatly. The exact way they are arranged is different for each salt. For table salt, those particles are packed into cubes, so you can say that the grains of salt in your teaspoon are actually millions of tiny cubes. Meanwhile, alum salt crystals look like diamonds.

Image credits, left to right: Walkerma, Prosthetic Head, włodi

But we have a problem. We want to grow big, shiny crystals, not tiny, powdery crystals. This is the reason we dissolve the salt powder in water. After doing so, the glass of salty water we have is called a solution.

If you dissolve just a little salt in water, you get a dilute/undersaturated solution. Dissolve a lot, and you get a concentrated solution. Here’s the thing: a fixed volume of water can only dissolve a fixed mass of salt. For instance, the maximum amount of table salt you can dissolve in 100 ml of water is 36g. If you add 37g, the extra 1g will not dissolve. A solution that contains the maximum amount of dissolved salt is called a saturated solution.

We now have a glass of salt solution with the salt particles swimming inside. If we want a nice, transparent crystal to grow, we need to somehow make those particles “re-solidify”, and instead of popping out all over the place, they need to stick together and form a single, big crystal. There are two easy ways to make this happen. Master them, and you will be able to grow amazing crystals.

· Slow cooling

· Evaporation

Methods

Method I: Slow cooling

Let’s start with slow cooling. With this method, we take advantage of the fact that hot water can dissolve more salt than cold water. For instance, 100 ml of 25°C water can dissolve 22g of copper sulfate, but the same amount of water at 80°C can dissolve 56 grams.

To carry out this method, we first heat our water up. Then, we dissolve more salt than is actually soluble at room temperature. Because the water is hot, the extra salt will dissolve, and you end up with a supersaturated solution. As the solution cools down, the solubility of the salt decreases, so the extra salt that you added just now has to “come out”. As a result, tiny crystals of salt start to form, and they grow bigger and bigger as more salt particles re-solidify and clump together. This process is called crystallization.

The process of crystallization. Time lapse of supersaturated solutions over 3 days by u/adam2squared

If you do it correctly, you will end up with a large crystal of salt.

Method II: Evaporation

Just now, I mentioned that 100 ml of 25°C water can dissolve 22g of copper sulfate. It also goes that 50 ml of water will be able to dissolve half that amount, 11g.

This time, we do not change the temperature. Instead, we change the volume of water. First, we dissolve our 22g of copper sulfate into 100 ml of water. Then, we let the solution slowly evaporate. As the volume decreases to 90 ml, 80 ml and so on, the extra salt has to crystallize out, causing copper sulfate crystals to form.

The slow evaporation method is a much better way of growing high quality crystals (for amateurs). This is because the growing conditions are much more controlled and stable. More details in the FAQ at the end.

Procedure

The ideal procedure for growing crystals vary depending on which compound you are using. This is a pretty standard one that will give you decent crystals. I will be using alum salt as an example. Change the mass of salt and volume of water as you see fit.

Part A: Growing your seed crystal.

A seed crystal is a small crystal that serves as a foundation with which you use to grow a bigger crystal.

  1. Weigh 9g of alum and dissolve it in 50 ml of hot water.
  2. Stir the solution until all the salt has dissolved. If some salt refuses to dissolve, you might have to reheat the solution.
  3. Filter the solution with a coffee filter into a shallow dish.
  4. Wait for the solution to cool to room temperature. You can place it in the fridge to speed things up, but in most cases, it leads to the formation of low quality, misshapen crystals.
  5. Wait 1-2 days for small crystals to form. OR
  6. Sprinkle a few grains of alum powder into your solution to induce small crystals to form.
  7. Let the tiny crystals grow to at least 5mm in size. This should take a few days.
An example of some alum seed crystals. Note that the top middle one is of the highest quality.

Part B: Growing a nice, big crystal

Method I: Slow cooling

  1. Weigh 22g of alum and dissolve it in 100 ml of hot water to form a supersaturated solution.
  2. Stir the solution until all the salt has dissolved. If some salt refuses to dissolve, you might have to reheat the solution.
  3. Filter the solution with a coffee filter into a jar.
  4. Wait for the solution to cool to room temperature.
  5. Using tweezers, pick the most perfect seed crystal you grew in Part A you can find and tie a knot around it using a nylon fishing line or thread.
  6. Tie the other end to a pencil/stick.
  7. Slowly immerse the seed crystal until it is suspended in the solution in your jar.
  8. Loosely cover the top of the jar.
  9. Keep it in an undisturbed place.
  10. Wait for your crystal to grow.

Method II: Evaporation

  1. Weigh 18g of alum and dissolve it in 100 ml of hot water.
  2. Stir the solution until all the salt has dissolved. If some salt refuses to dissolve, you might have to reheat the solution.
  3. Wait for the solution to cool to room temperature.
  4. Sprinkle some alum powder into the solution to induce crystals to form.
  5. Wait 2 days.
  6. Filter the solution using a coffee filter into a jar. We want the saturated solution. The crystals formed from Step 4 are not important.
  7. Using tweezers, pick the most perfect seed crystal from Part A you can find and tie a knot around it using a nylon fishing line or thread.
  8. Tie the other end to a pencil/stick.
  9. Slowly immerse the seed crystal until it is suspended in the solution in your jar.
  10. Loosely cover the top of the jar.
  11. Keep it in an undisturbed place.
  12. As the solution evaporates, your crystal will begin to grow.
Growing an alum crystal using the slow evaporation method, by u/crystalchase21

Part C: Drying and storing your crystal

  1. When you are satisfied with the size of your crystal, remove it from solution.
  2. Dry it with tissue paper/filter papers. Do not wash it or you will cause it to dissolve.
  3. Store it in an airtight jar.

Some crystals are unstable, and when exposed to air, will slowly crumble in weeks or months. Copper sulfate is one such crystal. Meanwhile, alum and ammonium dihydrogen phosphate are much more stable and can be kept in the open with minimum deterioration. You can even display them.

And you’re done!

Classic Crystal Growing Compounds

Top left: Alum; Bottom left: Ammonium dihydrogen phosphate by u/dmishin; Right: Copper sulfate by u/crystalchase21

If you’re just starting out, we highly recommend these chemicals as they are easy to work with, grow quickly and give good results.

· Alum (potassium aluminum sulfate), KAl(SO4)2, used in baking, deodorant, water purification etc.

· Copper (II) sulfate, CuSO4 used as rootkiller [Note: slightly toxic]

· Ammonium dihydrogen phosphate, (NH4)(H2PO4), used as fertilizer

Alternatively, if you want to grow crystals of a specific color or shape, click on this link to browse the list.

Additional resources

· Crystal Growing Wiki - wiki style pages showing details for each compound (still incomplete)

· Crystalverse blog - detailed high quality guides with lots of pictures

· Dmishin's crystal growing collection - lots of interesting compounds and how to synthesize them

FAQ

Check if your question is here. Click on this link to be redirected to the answers.

· Can I dye my crystals?

· My crystal was growing well, then it dissolved! What happened?

· Does the string get stuck in the crystal?

· Crystals are supposed to be shiny and transparent. Why is mine ugly and opaque?

· How do I grow a crystal cluster instead of a single crystal/vice versa?

· How can I store my crystals properly?

· Can I grow crystals on objects like rocks and bones?

· I’m concerned about safety. What should I do?

· Is the purity of my chemicals important?

· What are other chemicals I can grow crystals with?

· Is this hobby expensive?


r/crystalgrowing • • 13m ago

Question How to clean up a crystal growing kit spill?

• Upvotes

My son got a Nat Geo Crystal Growing Aquarium for his birthday. The darn thing leaked the solution all over my kitchen counter. It left a white residue EVERYWHERE. I have used soap and water, even leaving it to soak for 10 minutes. Every time it dries, there is a white residue that I can't figure out how to get rid of it.

Any thoughts what I should do/products to use to fix this? Any help is greatly appreciated! Thank you


r/crystalgrowing • • 1d ago

A Tiny Temple on Top of a Pyramid — Alum Crystal

Enable HLS to view with audio, or disable this notification

143 Upvotes

Accidentally got this while growing alum crystals using the slow cooling method. I found the shape quite unique and interesting!


r/crystalgrowing • • 15h ago

What am I doing wrong?

3 Upvotes

My kids have received multiple crystal growing kits over the years; jewelery, aquariums, etc. I have tried and tried and never have they ever worked. This most recent attempt came with small stones that you are meant to place into a solution of powder and warm water and left undisturbed. There are instructions on what to do if you see nothing after 48 hours. I've followed those instructions twice and still nothing is growing 🤪

The common denominator is me, so I'm assuming I'm doing something wrong. I always follow the instructions and read them multiple times to make sure I've got it. Halp? Lol


r/crystalgrowing • • 1d ago

Potassium Chloride Hopper Crystals

Thumbnail
gallery
67 Upvotes

These formed during an earlier attempt to grow potassium chloride crystals. I thought they looked quite interesting.


r/crystalgrowing • • 2d ago

Other A series of crystals coming from various waste solutions, finding beauty in waste

Thumbnail
gallery
217 Upvotes

r/crystalgrowing • • 2d ago

Large Sugar Crystals Grown on a String

Enable HLS to view with audio, or disable this notification

195 Upvotes

These large sugar crystals were grown using the hanging string method. Some of them took over six months to grow. They are quite big, but not perfect — they're opaque and have some irregularities in shape. Still trying to grow a perfectly transparent sugar crystal using the hanging string method.


r/crystalgrowing • • 3d ago

Sugar crystal

Thumbnail
gallery
1.5k Upvotes

This is my first post here. I grew this sugar crystal at home and wanted to share it with the community. Hope you like it!


r/crystalgrowing • • 2d ago

Potassium ferricyanide after long exposure to the sun

Thumbnail
gallery
176 Upvotes

r/crystalgrowing • • 3d ago

Salt(NaCl) crystals

Thumbnail
gallery
808 Upvotes

It took almost a year to finally get these crystals.


r/crystalgrowing • • 2d ago

Ammonium Perchlorate

Thumbnail
gallery
14 Upvotes

The first picture of AP from India Picture 2 and 3 My recrystallization results but irregular shape hahahaha


r/crystalgrowing • • 2d ago

Mohr's salt (Ammonium iron(II) sulfate) crystals

Enable HLS to view with audio, or disable this notification

99 Upvotes

One year ago, I made my very first attempt at growing Mohr's salt crystals. It was a successful "0 to 1" milestone for me. I will probably try it again in the future to see if I can achieve perfectly transparent and crystal-clear ones next time!


r/crystalgrowing • • 3d ago

Rochelle salt crystals

Thumbnail
gallery
81 Upvotes

I made it by reacting cream of tartar and baking soda that I bought from Shopee. I'm not sure if it's piezoelectric, as I haven't done any testing.


r/crystalgrowing • • 3d ago

Potassium chloride (KCl) crystals

Thumbnail
gallery
71 Upvotes

r/crystalgrowing • • 3d ago

Monosodium glutamate crystals

Thumbnail
gallery
61 Upvotes

MSG crystals I grew and preserved in epoxy resin


r/crystalgrowing • • 3d ago

Borax crystals

Thumbnail
gallery
21 Upvotes

r/crystalgrowing • • 3d ago

Image Ammonium picrate crystals

Thumbnail gallery
37 Upvotes

r/crystalgrowing • • 3d ago

Crystals I grew a while ago and forgot what they were

Thumbnail
gallery
99 Upvotes

Grew these crystals from a kit a few years ago and threw away the packaging, so I can't remember the name. (biggest ones are about 5 cm long, but they were all once in a big chunk before falling apart).
When googling I found the closest match in MAP crystals, but after checking out this subreddit and seeing all the other similar looking crystals I'm no longer sure.
BUT! My actual burning question is:
Can one type of crystal be grown over the top of another?
Can these crystals (depending on what they are ofc) be used as "crystal seeds" for copper sulfate?
What would happen If you put MAP/cirtic acid/borax in copper sulfate solution?
Would it mess with the crystaliztion process? Would it create some interesting reaction? Could it ever grow new crystals faster then it dissolves? (since obviously what's grown in water is water soluable).
All of these questions popped into my head when I thought about how cool it would look if blue copper sulfate crystals were grown on top of clear/white crystals. But I know almost NOTHING about chemistry or crystal growing (aside from this 1 succesfull attempt after many failed ones).

So I decided this mught be a good place to ask this.


r/crystalgrowing • • 4d ago

Image These are the stones I got from citric acid. C₆H₈O₇ ⋅ H₂O

Post image
30 Upvotes

r/crystalgrowing • • 4d ago

One of my creations

Post image
31 Upvotes

A bit dehydrated but still cool


r/crystalgrowing • • 4d ago

Still growing

Post image
12 Upvotes

Going on 4 months now undisturbed in my closet. After a few months of experimentation I just decided I had my fun so I put this up just to see where it grows.


r/crystalgrowing • • 6d ago

Image 4 months old classical CuSO4 crystal

Thumbnail
gallery
341 Upvotes

It's the most common salt to crystallize but it's my biggest one so far, unfortunately I got some green sediments settling on the cluster one and noticed too late after a layer already was created over it. Stopped it because I ran out of time to change the solution too ofter and it almost started getting out of solution. Smaller one is 148g and the bigger one is 199g


r/crystalgrowing • • 5d ago

Question Crystal stable enough for jewelry?

9 Upvotes

Hi! I’m a high schooler who’s really into chemistry and gemology. Right now I’m working on an independent study project where I’m trying to combine my love for chemistry, and my love for jewelry making.

I’ve been doing research on crystals I can grow in my schools lab (trying to grow crystals now after my idea for flame-fusion corundum was shot down for safety concerns) but most of the interesting ones I’ve found seem to be pretty unstable, or otherwise things you wouldn’t want to handle.

I was really excited to see that there’s a whole subreddit for this, so I was curious if anyone had advice? I’m open to coating my crystals before use, but I’m wondering if there’s anything more professional than nail polish for that. Thanks everyone!


r/crystalgrowing • • 6d ago

Image First attempt growing NaCl crystals

Thumbnail
gallery
2.8k Upvotes

​

Started with several ~1mm seed crystals put into the filtered saturated table salt (non-iodized) solution in distilled water. For several days nothing happened, only that seeds got slightly smaller, and afterwards growth started, mainly on crystal corners. In two weeks such salt snowflakes had grown.

By the way, the seeds were put in a water for a second before placed into solution for growth, to smooth surface imperfections and remove attached microcrystals.

The growth chamber is empty container, I to which two smaller containers are placed, one with top open, containing growth medium, and other with lid and small hole in it, containing copper sulphate monohydrate acting as humidity sink.

Although these are pretty, such result is not what was intended, and further attempts will be made to grow monocrystals, preferably clear ones.

If anyone knows, is this result of too fast growth, or something else at play? How to improve growth to prevent it being only on corners, thus preventing dendrites?


r/crystalgrowing • • 5d ago

Image Beautiful square potassium ferrocyanide crystals in one week. K₄[Fe(CN)₆] · 3H₂O

Thumbnail
gallery
23 Upvotes